At the beginning of turn 2, you have a 1 in 6 chance of drawing Doctor.
If you don't draw Doctor (5 in 6), you'll get it in turn 3; your draw deck is only 5 cards anyway.
If you do draw Doctor on turn 2, then you play it. Say you trash one card and you buy a Silver. Your draw deck is now 4 cards. On turn 3, you draw one card from (shuffled) discard, 1 or 6 which is Doctor (note that you have total 10 cards; each time you delete a card with Doctor, you've replaced it with something else). Hence, you had a 1 in 6 chance of drawing Doctor on turn 2; then a 1/6 * 1/6 chance of drawing it on turn 3. The probability is 1/36 + 5/6 = 86%, not 83%.
However, the exact probability is not really something you can calculate because it depends on player decisions -- which card you choose to name, which card you choose to buy, etc. If you draw Doctor on turn 2, your draw deck is CCCEE, and you have a legitimate choice between naming C and E (E is probably better, but in some cases C may be better). Instead of buying Silver, you might certainly buy a card like Wishing Well or Village, etc, which would serve as a cantrip.