Ignoring reshuffles, Estates vs Coppers, Estates in discard vs Estates in hand, multiple Peddlers or multiple Scrying Pools, etc.... I think that while the expected draw might be the same either way, there's a big risk vs reward issue at stake.
Pretend you have 99 actions and only 2 Estates in your deck, with one Estate on top. So the other Estate has a 1 in 100 chance of being in each spot of your deck. 3 possible situations:
1) If the Estate is the very bottom card, then it makes no difference at all what order you play them in; you draw your whole deck. (1% chance)
2) If the Estate is the second from the top, then playing your Scrying Pool first means you draw nothing. Playing your Peddler first means you draw your deck. (1% chance)
3) If the Estate is in any other position at all (X from the top), then playing your Peddler first means drawing X cards, and playing your Scrying Pool first means drawing X+1 cards. (98% chance)
As you can see, 98% of the time it is better to play your Scrying Pool first. However, it is only better by 1 card. The 1% of the time where playing your Peddler first is better, it is 100 times better.
This same basic logic/math should work even when you add other dead cards into the deck.