I find it interesting to hear/realize that pile shuffling is reversible, because that could have a crazy application for MtG: if someone plays a game, pile shuffles, then riffle/mash shuffles only one or two times, then when the other opponent takes their right to shuffle the deck, they could perform a procedure that reverses the pile shuffle, then perform no other randomization. The player who underrandomized would then have a very high likelihood of getting clumpy draws.
.. and the other player gets DQed for cheating.
Stacking your opponents deck intentionally is illegal.
Well, there's two thing here, theory, and practice. In practice, I think you'd have a really hard time proving malicious intent from the person who reversed the pile shuffle. I don't think anyone would ever get DQed for reversing a pile shuffle. At the RELs that are high enough where a DQ like that would happen, both players are going to be megarandomizing their decks so much this will not be not really be a thing.
In theory, apart from what may be Wizards of the Coast policy because I don't always agree with that, when your opponent presents their deck to you, it's already random, and it was their responsibility to make sure of that, and if I don't look at the faces of the cards there's nothing I can do to make it nonrandom. If you reverse a procedural reordering on the cards, you can't possibly make your opponent's draws any better or any worse unless he didn't randomize his deck in the first place. If he didn't randomize his deck in the first place, then you stacked his deck with a procedural method, but that by necessity means that he did too when he pile shuffled procedurally. The only way a rational arbiter could DQ the second player to touch the cards is if he also DQ'ed the first player to touch the cards. Double DQing could be an internally consistent position to have on that though.
Philosophically, I don't really think that a form of "cheating" that in its absolute best case reverses the amount of cheating an opposing player did can really be considered cheating.
As a specific exception, if someone performed the "semirandom pile shuffle", where they try to pick which pile gets each card as arbitrarily as they possibly can, and you managed to watch and remember what they chose for each pile, which would be impressive, and then reversed -that-, that would be cheating, because there was some amount of randomness and disorder in how those piles were created (even though human random number generation is really weak, which is why that method shouldn't relied upon), and you've reversed that randomness and disorder deliberately.