Let's look at the shuffles on turns 3-4 for Witch/- versus Witch/Copper
Witch/-
AAAAA/BBBBB/C
(5/11): Play witch on turn 3. Draw 4 cards, trigger a shuffle, draw a card (1/8 chance of drawing witch again) - Great!
(5/11): Play witch, draw a card, shuffle 6 cards into deck, draw again - Slightly below average
(1/11): Witch misses shuffle - Ouch!
Witch/Copper
AAAAA/BBBBB/CC
(5/12): Play witch - Average
(5/12): Play witch - Average
(2/12): Witch misses shuffle - Ouch!
For a Witch/- opening, (5 card hand + 5 card hand + witch = 12 cards drawn with an 11 card deck) which triggers a shuffle early. The cards drawn on turn 3 are likely to be drawn again on turn 5. This means that drawing witch in the first 5 cards is great, drawing in then second 5 is OK, and drawing the witch as the 11th card is terrible.
For Witch/Copper, there's a 10/12 chance of a full shuffle at the start of turn 5 and a 2/12 chance of the witch missing the shuffle.
In conclusion, Witch/- seems better than Witch/Copper overall, and having witch in the top 5 cards of the shuffle is a big boost.